A REGIOSELECTIVE ONE-POT SYNTHESIS AND SYNTHETIC APPLICATIONS OF CYANODEOXY SUGARS BY CYANOTRIMETHYLSILANE

Citation
Snuh. Kazmi et al., A REGIOSELECTIVE ONE-POT SYNTHESIS AND SYNTHETIC APPLICATIONS OF CYANODEOXY SUGARS BY CYANOTRIMETHYLSILANE, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 50(2), 1995, pp. 294-302
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
09320776
Volume
50
Issue
2
Year of publication
1995
Pages
294 - 302
Database
ISI
SICI code
0932-0776(1995)50:2<294:AROSAS>2.0.ZU;2-7
Abstract
The regioselective epoxide opening of different 2,3-anhydropyranoses b y cyanotrimethylsilane is investigated. The isolated cyanodeoxy pyrano ses allow easy access to the corresponding branched-chains aminomethyl sugars by lithium aluminium hydride reduction or sugar amides by cont rolled acid hydrolysis.