AQUEOUS VANADOSILICATES

Citation
Ow. Howarth et Jj. Hastings, AQUEOUS VANADOSILICATES, Journal of the Chemical Society. Dalton transactions, (22), 1996, pp. 4189-4192
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03009246
Issue
22
Year of publication
1996
Pages
4189 - 4192
Database
ISI
SICI code
0300-9246(1996):22<4189:AV>2.0.ZU;2-H
Abstract
Silicate anions were shown by V-51 and O-17 NMR spectroscopy to combin e with aqueous [HVO4](2-) in aqueous alkaline solution, forming the an ions [H2VSiO7](3-), [H3VSiO7](2-) and various related monovanadooligos ilicate species. Approximate equilibrium constants have been derived; and shown to depend only weakly upon ionic strength. The ion [H2VSiO7] (3-) at higher concentrations also dimerises to give an anion with a S iOVOVOSi linkage, as shown by selective inversion-transfer subtraction spectra.