SYNTHESIS OF METHYL (D-GLYCOPYRANOSYL AZIDE)URONATES

Authors
GYORGYDEAK Z THIEM J
Citation
Z. Gyorgydeak et J. Thiem, SYNTHESIS OF METHYL (D-GLYCOPYRANOSYL AZIDE)URONATES, Carbohydrate research, 268(1), 1995, pp. 85-92
Citations number
51
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Carbohydrate research → ACNP
ISSN journal
00086215
Volume
268
Issue
1
Year of publication
1995
Pages
85 - 92
Database
ISI
SICI code
0008-6215(1995)268:1<85:SOM(A>2.0.ZU;2-Q
Abstract
Sodium hypochlorite oxidation catalysed by 2,2,6,6,-tetramethylpiperid ine 1-oxide (TEMPO) is shown to be a mild and efficient approach to th e title uronates. In the gluco, galacto, allo, and 2-acetamido-2-deoxy -gluco series, the corresponding beta- or alpha- and beta-glycosyl azi des could be smoothly oxidised and alternative preparations are compar ed to this access.