NEW SELECTIVE SYNTHESES OF (METH)ACRYLIC MONOMERS - ISOCYANATES, ISOCYANURATES, CARBAMATES AND UREAS DERIVATIVES

Authors
DUBOSCLARDGOTTARDI C CAUBERE P FORT Y
Citation
C. Dubosclardgottardi et al., NEW SELECTIVE SYNTHESES OF (METH)ACRYLIC MONOMERS - ISOCYANATES, ISOCYANURATES, CARBAMATES AND UREAS DERIVATIVES, Tetrahedron, 51(9), 1995, pp. 2561-2572
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
9
Year of publication
1995
Pages
2561 - 2572
Database
ISI
SICI code
0040-4020(1995)51:9<2561:NSSO(M>2.0.ZU;2-Y
Abstract
The selective formation of omega-isocyanatoalkyl (meth)acrylates may b e conveniently obtained by simple condensation of potassium cyanate wi th omega-halogeno-alkyl (meth)acrylates under appropriated phase trans fer catalytic conditions. Depending on the reaction media and the temp erature, these isocyanate derivatives may be isolated, trimerized to t he corresponding isocyanurates or trapped in situ as carbamates or ure as compounds.