SYNTHESIS AND REACTIVITY OF 1-N,N-DIETHYLCARBAMOYL-1,3-BUTADIENE

Authors
MASON PH EMSLIE ND
Citation
Ph. Mason et Nd. Emslie, SYNTHESIS AND REACTIVITY OF 1-N,N-DIETHYLCARBAMOYL-1,3-BUTADIENE, Tetrahedron, 51(9), 1995, pp. 2673-2678
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
9
Year of publication
1995
Pages
2673 - 2678
Database
ISI
SICI code
0040-4020(1995)51:9<2673:SARO1>2.0.ZU;2-M
Abstract
1-N,N-Diethylcarbamoyl-1,3-butadiene is easily prepared from cis-1,4-d i(N, N-diethylcarbamoyl)but-2-ene and reacts, as the vinyl anion, with various electrophiles. The preparation of the diene demonstrates the leaving ability of the N, N-dialkylcarbamoyl group.