A STUDY OF THE SCOPE OF THE BISMETHOXYCARBONYLATION OF NORBORNENE SYSTEMS

Authors
JOLLIFFE K PADDONROW MN
Citation
K. Jolliffe et Mn. Paddonrow, A STUDY OF THE SCOPE OF THE BISMETHOXYCARBONYLATION OF NORBORNENE SYSTEMS, Tetrahedron, 51(9), 1995, pp. 2689-2698
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
9
Year of publication
1995
Pages
2689 - 2698
Database
ISI
SICI code
0040-4020(1995)51:9<2689:ASOTSO>2.0.ZU;2-N
Abstract
Stille-Vogel bismethoxycarbonylation of a series of norbornene-type mo noenes, 9-15, and nonconjugated dienes, 16 and 17 was studied. Three s ignificant findings ate: (1) Bismethoxycarbonylation reactions may be carried out using CO at atmospheric pressure. (2) The sensitive p-meth oxybenzyl protecting group withstands the Stille-Vogel reaction condit ions. (3) The bismethoxycarbonylation reaction may be carried out usin g THF as a cosolvent, although reaction times are longer.