Sf. Steeneken et al., CHANGES IN TRANSMISSION CHARACTERISTICS OF POLYMETHYLMETHACRYLATE ANDCELLULOSE-(III) ACETATE DURING EXPOSURE TO ULTRAVIOLET-LIGHT, Photochemistry and photobiology, 61(3), 1995, pp. 276-280
Ultraviolet-transparent polymethylmethacrylate (PMMA) and cellulose (I
II) acetate (CA) (often used as a cut-off filter in UVB [280-320 nm] b
iological effect studies) were exposed to a 20 W Philips TL 12 lamp to
examine changes in transmission characteristics due to UVB exposure.
Transmission of UVB and biologically weighted UVB (UVBBE(DNA)) through
PMMA were similar, 88.3 and 83.5%, respectively. The absorption chara
cteristics of PMMA did not change with time at any of the UV irradianc
e levels applied. However, transmission of UVB and UVBBE(DNA) through
new CA differed considerably: 59% versus only 11%, respectively. Also,
spectral absorption characteristics changed with time due to degradat
ion of CA, at a rate that was dependent on the incident UVB irradiance
. The decrease in transmission through CA of both UVB and UVBBE(DNA) c
an be described by exponential functions. The CA that was wrapped arou
nd the UV lamp showed dramatic changes in UV absorption over the first
few hours of use. However, when CA was placed at a longer distance fr
om the light source initial degradation was less. It is concluded that
PMMA can be applied in UV effect studies as a reasonable alternative
for quartz. The CA should, however, be used with care, because the lar
ge transmission decreases that were observed strongly hamper an accura
te calculation of (biologically weighted) UVB dose rates.