BEHAVIOR OF TRANSPLUTONIUM ELEMENTS ON THIN-LAYER SILICA-GEL USING DI-2-ETHYLHEXYLPHOSPHORIC ACID

Authors
MOLOCHNIKOVA NP MYASOEDOV BF
Citation
Np. Molochnikova et Bf. Myasoedov, BEHAVIOR OF TRANSPLUTONIUM ELEMENTS ON THIN-LAYER SILICA-GEL USING DI-2-ETHYLHEXYLPHOSPHORIC ACID, Radiochemistry, 36(4), 1994, pp. 348-352
Citations number
23
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
Radiochemistry → ACNP
ISSN journal
10663622
Volume
36
Issue
4
Year of publication
1994
Pages
348 - 352
Database
ISI
SICI code
1066-3622(1994)36:4<348:BOTEOT>2.0.ZU;2-V
Abstract
The behavior of transplutonium elements (TPE) on thin-layer silica gel on domestic sorbphil thin-layer chromatography (TLC) plates is invest igated using di-2-ethylhexylphosphoric acid (D2EHPA) solutions in HNO3 of various concentrations. Conditions are found for separating Bk(IV) from other TPE in solutions with [HNO3] > 5 M and also for separating Bk(III) and Ce. Solutions of D2EHPA as the mobile phase are recommend ed for TLC identification of tracer amounts of different oxidation sta tes Am in HNO3.