OXIDATIVE ADDITION OF DIFERROCENYL DICHALCOGENIDES TO [(RU(ETA(5)-C(5)ME(5))-(MU(3)-CL))(4)] - SYNTHESES, CRYSTAL-STRUCTURES AND SOME REACTIVITIES OF [(RU(ETA(5)-C(5)ME(5))CL(MU-ER))(2)] (E=S, SE OR TE - R EQUALS FERROCENYL)

Authors
MATSUZAKA H QU JP OGINO T NISHIO M NISHIBAYASHI Y ISHII Y UEMURA S HIDAI M
Citation
H. Matsuzaka et al., OXIDATIVE ADDITION OF DIFERROCENYL DICHALCOGENIDES TO [(RU(ETA(5)-C(5)ME(5))-(MU(3)-CL))(4)] - SYNTHESES, CRYSTAL-STRUCTURES AND SOME REACTIVITIES OF [(RU(ETA(5)-C(5)ME(5))CL(MU-ER))(2)] (E=S, SE OR TE - R EQUALS FERROCENYL), Journal of the Chemical Society. Dalton transactions, (22), 1996, pp. 4307-4312
Citations number
60
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
22
Year of publication
1996
Pages
4307 - 4312
Database
ISI
SICI code
0300-9246(1996):22<4307:OAODDT>2.0.ZU;2-1
Abstract
Reaction of [{Ru(eta(5)-C(5)Me(5))(mu(3)-Cl)}(4)] with 2 equivalents o f REER (E = S, Se or Te; R = ferrocenyl) gave novel ferrocenylchalcoge nolate-bridged diruthenium complexes [{Ru(eta(5)-C(5)Me(5))CI(mu-ER)}( 2)] in good yields. Reduction of these by sodium amalgam in the presen ce of buta-1,3-diene afforded Ru(eta(5)-C(5)Me(5))(mu-ER)}(2)(mu-s-tra ns-eta(2): eta(2)'-CH2=CHCH=CH2)], whereas treatment with AgOSO2CF3 pr oduced,the co-ordinatively unsaturated complexes )Me(5))Ru(mu-ER)(2)Ru (eta(5)-C(5)Me(5))][OSO2CF3]. The structures of five of the complexes have been defined by X-ray crystallography.