SYNTHESIS, OXIDATION AND CLAISSEN REARRANGEMENT OF 4-(ALLYLOXY)PHENYL-1,4-DIHYDROPYRIDINES AND 4-(ALLYLOXY)PHENYL-1,4-DIHYDROPYRIMIDINES

Authors
SAR CP HANKOVSZKY OH JERKOVICH G PALLAGI I HIDEG K
Citation
Cp. Sar et al., SYNTHESIS, OXIDATION AND CLAISSEN REARRANGEMENT OF 4-(ALLYLOXY)PHENYL-1,4-DIHYDROPYRIDINES AND 4-(ALLYLOXY)PHENYL-1,4-DIHYDROPYRIMIDINES, ACH, models in chemistry, 131(3-4), 1994, pp. 363-376
Citations number
24
Categorie Soggetti
Chemistry
Journal title
ACH, models in chemistry → ACNP
ISSN journal
12178969
Volume
131
Issue
3-4
Year of publication
1994
Pages
363 - 376
Database
ISI
SICI code
1217-8969(1994)131:3-4<363:SOACRO>2.0.ZU;2-R
Abstract
1,4-Dihydropyridines and -pyrimidines can be oxidized conveniently to pyridine and pyrimidine with active MnO2 with or without cleavage of t he 4-substituent. In a TiCl4 catalyzed reaction ortho-Claisen rearrang ement takes place with both 4-(2-allyloxy)phenyl 1,4-dihydropyridines and -1,4-dihydropyrimidines.