A fundamental study into the breakdown of aspen and bitch fibres was u
ndertaken to provide a better understanding of the peeling and fibrill
ation processes that occur during chip refining of hardwoods. Fibres o
f TMI: CTMP and CMP pulps were analyzed in cross-section. The degrees
to which the compound middle lamella and outer secondary wall (S-1 lay
er) were retained, and the S-2 layer exposed were recorded Higher prop
ortions of S-2 layers were exposed in TMP fibres compared with CTMP an
d CMP fibres. Alkaline sulphite pretreatment of chips did not improve
the degree of S-2 layer exposure of the extent of fibrillation of the
fibres. These treated fibres retained most of their compound middle la
mellae. Pulp strength was,rot related to the degree of exposure of the
S-2 layer but rather closely followed fibre flexibility (as measured
by sheet density). Thus, despite the apparently superior bonding poten
tial of TMP fibres (large exposure of S-2 layer), the fibres remained
stiff and produced sheets with low density and strength.