This study developed Kuhn-Mark-Houwink-Sakurada (KMHS) equations for k
raft lignin, based on the absolute molecular weight characterized with
low-angle laser light scattering. The KMHS exponential factors of kra
ft lignin were found to be 0.11, 0.13 and 0.23 in dimethylformamide (D
MF) at 318.2 K, in DMF at 350.7 K and in 0.5 N sodium hydroxide at 303
.2 K, respectively. Lignin molecules in solution are approximately sph
erical particles and slightly solvated with solvent.