STABLE PRODUCTS AND SOME KINETIC FEATURES OF DICHLOROSILANE-AIR COMBUSTION

Citation
Rg. Aivazyan et al., STABLE PRODUCTS AND SOME KINETIC FEATURES OF DICHLOROSILANE-AIR COMBUSTION, Kinetics and catalysis, 36(2), 1995, pp. 168-173
Citations number
15
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00231584
Volume
36
Issue
2
Year of publication
1995
Pages
168 - 173
Database
ISI
SICI code
0023-1584(1995)36:2<168:SPASKF>2.0.ZU;2-U
Abstract
The amounts of H-2, HCl, and H2O in the reaction products of the combu stion of dichlorosilane-air mixtures containing from 1 to 100% of dich lorosilane were determined. The explosion concentration limits (2.5 an d 94%) were estimated under standard conditions and the effect of an i nert gas (N-2) On these limits was studied. The promoting action of di chlorosilane oxidation on its decomposition and on two-stage explosion , which is accompanied by a propagation of a chemical reaction wave in a closed volume, was established.