EFFECT OF A LIQUID-PHASE ON SPILLOVER OF HYDROGEN

Authors
KILDIBEKOVA GA ZAVYALOV SA MIKHAILENKO SD
Citation
Ga. Kildibekova et al., EFFECT OF A LIQUID-PHASE ON SPILLOVER OF HYDROGEN, Kinetics and catalysis, 36(2), 1995, pp. 256-259
Citations number
11
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
36
Issue
2
Year of publication
1995
Pages
256 - 259
Database
ISI
SICI code
0023-1584(1995)36:2<256:EOALOS>2.0.ZU;2-T
Abstract
Spillover of hydrogen in Pt/ZnO is studied by measuring conductance of semiconductor sensors in the presence of water and alcohol vapors. Th e sensor conductance is found to increase sharply at low solvent press ures and to decrease significantly with increasing pressure. The effec ts observed are interpreted from the standpoint of accelerating the tr ansfer of atomic hydrogen by solvation and desolvation of a proton.