EXAFS STUDY OF THE ORGANOMETALLIC POLYMERS PDNC60 STRUCTURE

Authors
CHERNOV VA IVANOVA VN KOZHEVNIKOVA AN MARDEZHOVA GA NIKITENKO SG NIKIFOROV AA
Citation
Va. Chernov et al., EXAFS STUDY OF THE ORGANOMETALLIC POLYMERS PDNC60 STRUCTURE, Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment, 359(1-2), 1995, pp. 250-253
Citations number
13
Categorie Soggetti
Nuclear Sciences & Tecnology","Physics, Particles & Fields","Instument & Instrumentation",Spectroscopy
Journal title
Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment → ACNP
ISSN journal
01689002
Volume
359
Issue
1-2
Year of publication
1995
Pages
250 - 253
Database
ISI
SICI code
0168-9002(1995)359:1-2<250:ESOTOP>2.0.ZU;2-#
Abstract
A series of new organometallic polymers, PdnC60, with varying Pd/C-60 ratios wets prepared and studied using EXAFS spectroscopy. The Pd K-ed ge EXAFS analysis suggests that the Pd atoms act as bridges between ad jacent C-60 molecules by coordination to the pi-electrons of their dou ble bonds. The distance between the Pd atom and the nearest carbon ato ms Pd-C-1 (2.27(3) Angstrom) is found to be somewhat longer than that in typical Pd(O)-olefin pi-complexes.