PICOSECOND TIME-RESOLVED FOURIER-TRANSFORM RAMAN-SPECTROSCOPY OF 9,10-DIPHENYLANTHRACENE IN THE EXCITED SINGLET-STATE

Time-resolved Fourier transform Raman spectroscopy of the highly fluor escent chromophore 9,10-diphenylanthracene (DPA) in cyclohexane and et hanol is described. Raman spectra of the first excited singlet state o f DPA were obtained with 100-ps resolution at several time delays betw een pump pulses at 355 nm and probe pulses at 1064 nm. The near-infrar ed excited-state Raman scattering is enhanced by resonance with an exc ited-state transition of DPA. The excited-state Raman bands decay in a bout 5-6 ns. Evidence for interaction of the solvent with the DPA exci ted state is observed in the cyclohexane C-H stretching bands.