Rs. Juang et Tc. Chou, KINETICS OF THERMAL-DECOMPOSITION OF AZOBISISOBUTYRONITRILE IN HETEROGENEOUS MEDIA, Journal of the Chinese Institute of Chemical Engineers, 26(2), 1995, pp. 89-94
In this paper, the rate of thermal decomposition of azobisisobutyronit
rile (AIBN) in a liquid paraffin was measured. at 363 K wherein AIBN p
article was not completely dissolved and decomposed at the early stage
s of overall decomposition process. A kinetic model was proposed to de
scribe the decomposition process of AIBN before complete dissolution.
The influence of the catalyst SnCl4 on AIBN decomposition in heterogen
eous media was also investigated.