KINETICS OF THERMAL-DECOMPOSITION OF AZOBISISOBUTYRONITRILE IN HETEROGENEOUS MEDIA

Authors
Citation
Rs. Juang et Tc. Chou, KINETICS OF THERMAL-DECOMPOSITION OF AZOBISISOBUTYRONITRILE IN HETEROGENEOUS MEDIA, Journal of the Chinese Institute of Chemical Engineers, 26(2), 1995, pp. 89-94
Citations number
14
Categorie Soggetti
Engineering, Chemical
ISSN journal
03681653
Volume
26
Issue
2
Year of publication
1995
Pages
89 - 94
Database
ISI
SICI code
0368-1653(1995)26:2<89:KOTOAI>2.0.ZU;2-B
Abstract
In this paper, the rate of thermal decomposition of azobisisobutyronit rile (AIBN) in a liquid paraffin was measured. at 363 K wherein AIBN p article was not completely dissolved and decomposed at the early stage s of overall decomposition process. A kinetic model was proposed to de scribe the decomposition process of AIBN before complete dissolution. The influence of the catalyst SnCl4 on AIBN decomposition in heterogen eous media was also investigated.