To improve the CFCs characteristics of chemical erosion, tritium reten
tion, and H2O/air resistivity, silicon doped CFCs were developed in th
e framework of European Fusion Technology programme. The tritium reten
tion, H2O reaction kinetics, outgassing behaviour and depletion of sil
icon in doped CFCs were investigated as a function of silicon concentr
ation and temperature. The results show that silicon in bulk of CFCs d
ecreases the tritium bulk retention and the H2O reactivity. However, i
t has been observed that the concentration of silicon is slightly decr
eased at elevated temperature. This paper presents the experimental re
sults and the consequence is discussed.