HYDROGEN-BONDING, PROTEON MOBILITY, STRUC TURE AND ELECTRON-TRANSFER IN POLYANILINES

Molecular structure models are proposed and discussed for various form s of polyaniline (base and salt forms, methyl, methoxy, chloro or fluo ro orthosubstituted derivatives) on the basis of X-ray diffraction, IR absorption and Raman scattering on films cast from NMP solution and p owders with or without grinding. Models are used to discuss both proto nic and electronic conductivity.