Jn. Cloutier et al., ELECTROLYSIS OF WEAK BLACK LIQUOR .2. EFFECT OF PROCESS PARAMETERS ONTHE ENERGY EFFICIENCY OF THE ELECTROLYTIC CELL, Journal of Applied Electrochemistry, 25(5), 1995, pp. 472-478
laboratory study of the effects of process parameters on the performan
ce of weak black liquor (WBL) electrolysis cells showed that anode mat
erial, current density and temperature are critical to the operation.
The two latter variables showed an interaction effect upon the operati
on of the cell. In terms of energy efficiency, the IrO2 anode performe
d better than the Pt anode. The addition of sodium sulfate to the WBL
was beneficial to the energy efficiency. No chlorine gas was produced
when electrolyzing WBL containing sodium chloride within the pH range
5.4 to 13.