In the Qinling mobile belt, Central China, Proterozoic metamorphic roc
ks (age of metamorphism about 990 Ma) were deformed and partly reequil
ibrated during the Caledonian orogeny (age about 440 Ma). The Caledoni
an activity occurred mainly along prominent shear zones, which extend
in an east-west direction. These relationships are well-illustrated in
the Beikwangping-Banqiao area (Kwangping group), where three Proteroz
oic metamorphic zones (lower and upper greenschist and lower amphiboli
te grades) are bounded by two Caledonian shear zones (Maheko and Jaoan
gou). Each structural unit shows a characteristic foliation: S1 (Prote
rozoic) and S2a and S2b (Caledonian). Three types of fluid inclusions
were observed during a detailed study of seven samples with comparable
lithology (quartz-rich sediments) and well-defined microstructural ch
aracteristics. The Proterozoic samples (S1) showed an evolution from p
urely aqueous fluids in the lowest metamorphic grade to dominant gaseo
us inclusions (pure CO2) in the highest grade (lower amphibolite). In
the Caledonian shear zones, the earliest fluids (S2a) were low-salinit
y, purely aqueous fluids introduced during large-scale thrusting. Late
r fluids (S2b) were hotter, complex mixtures of gases (CO2 with variab
le amounts of CH4 and N-2) and aqueous fluids of variable salinities e
mplaced in discrete, less ductile zones of deformation, which were for
med at the end of the thrusting.