SYNTHESIS OF THE C(3)-C(15) SEGMENT OF RUTAMYCIN-B VIA A C(8)-C(9) FRAGMENT ASSEMBLY ALDOL REACTION - METAL DEPENDENCE OF THE ALDEHYDE AND ENOLATE DIASTEREOFACIAL SELECTIVITIES

Authors
GUSTIN DJ VANNIEUWENHZE MS ROUSH WR
Citation
Dj. Gustin et al., SYNTHESIS OF THE C(3)-C(15) SEGMENT OF RUTAMYCIN-B VIA A C(8)-C(9) FRAGMENT ASSEMBLY ALDOL REACTION - METAL DEPENDENCE OF THE ALDEHYDE AND ENOLATE DIASTEREOFACIAL SELECTIVITIES, Tetrahedron letters, 36(20), 1995, pp. 3447-3450
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
20
Year of publication
1995
Pages
3447 - 3450
Database
ISI
SICI code
0040-4039(1995)36:20<3447:SOTCSO>2.0.ZU;2-X
Abstract
The diastereofacial selectivities of aldehyde 2b and ketone 3 are meta l dependent, and their fragment assembly aldol coupling is a matched d ouble asymmetric reaction when a chlorortitanium enolate is used.