FORMATION OF PORPHYRIN DONOR-ACCEPTOR COMPLEXES VIA AN AMIDINIUM-CARBOXYLATE SALT BRIDGE

Authors
KIRBY JP VANDANTZIG NA CHANG CK NOCERA DG
Citation
Jp. Kirby et al., FORMATION OF PORPHYRIN DONOR-ACCEPTOR COMPLEXES VIA AN AMIDINIUM-CARBOXYLATE SALT BRIDGE, Tetrahedron letters, 36(20), 1995, pp. 3477-3480
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
20
Year of publication
1995
Pages
3477 - 3480
Database
ISI
SICI code
0040-4039(1995)36:20<3477:FOPDCV>2.0.ZU;2-X
Abstract
Porphyrins have been modified with an amidine functional group and the y have been shown to bind carboxylic acids to form a amidinium-carboxy late salt bridge. These systems offer a new model to probe the mechani sm of proton-coupled electron transfer (PCET).