ASYMMETRIC CLEAVAGE OF CHIRAL ALPHA,BETA-ETHYLENIC ACETALS BY ORGANOLITHIUM REAGENTS

Authors
ALEXAKIS A MHAMDI F LAGASSE F MANGENEY P
Citation
A. Alexakis et al., ASYMMETRIC CLEAVAGE OF CHIRAL ALPHA,BETA-ETHYLENIC ACETALS BY ORGANOLITHIUM REAGENTS, Tetrahedron : asymmetry, 7(12), 1996, pp. 3343-3346
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
12
Year of publication
1996
Pages
3343 - 3346
Database
ISI
SICI code
0957-4166(1996)7:12<3343:ACOCAA>2.0.ZU;2-U
Abstract
alpha,beta-Ethylenic chiral acetals react regio- and stereoselectively with organolithium reagents. The obtained enol ether may be hydrolyze d into a chiral beta-disubstituted aldehyde. Copyright (C) 1996 Elsevi er Science Ltd