A NEW EXAMPLE OF STEREOISOMERISM IN INORGANIC-CHEMISTRY - PT-RU CHIRAL AXIS IN TA(6)-P-CYMENE)RUCL(MU-N,N'-DIALKYLDITHIOX-AMIDATO N,N'-RU-S,S'PT)PT(2-DIPHENYLPHOSPHINOPYRIDINE)CL]

Authors
LANZA S BRUNO G NICOLO F SCOPELLITI R
Citation
S. Lanza et al., A NEW EXAMPLE OF STEREOISOMERISM IN INORGANIC-CHEMISTRY - PT-RU CHIRAL AXIS IN TA(6)-P-CYMENE)RUCL(MU-N,N'-DIALKYLDITHIOX-AMIDATO N,N'-RU-S,S'PT)PT(2-DIPHENYLPHOSPHINOPYRIDINE)CL], Tetrahedron : asymmetry, 7(12), 1996, pp. 3347-3350
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
12
Year of publication
1996
Pages
3347 - 3350
Database
ISI
SICI code
0957-4166(1996)7:12<3347:ANEOSI>2.0.ZU;2-#
Abstract
The novel compounds [(eta(6)-p-cymene)RuCl(mu-RR-DTO N,N'Ru S,S'-Pt)Pt (RR-DTO)(P-N)Cl] (P-N = 2-diphenylphosphino-pyridine, RR-DTO N,N'-dial kyldithioxamidato, R = benzyl, 1; R = (R)-(-)-2-hydroxypropyl (coming from (R)-(-)-2-hydroxypropyl-amine), 2; exhibit a Pt-Ru chiral axis wh ich is a new example of stereoisomerism in inorganic chemistry. The cr ystal structure of 2 is also reported. Copyright (C) 1996 Elsevier Sci ence Ltd