The first observation of optical properties of new rare-earth-doped vi
treous fluoride waveguides has been recently reported. These vitreous
fluoride films have been deposited by a physical vapour deposition tec
hnique on fluoride substrates. Several PZG films and sandwiches deposi
ted on various substrates have been prepared with thickness of a few p
m and doped in the guiding layer by various amounts of erbium and othe
r rare-earth ions. High delta n/n (10(-2)) has been achieved as a resu
lt of the glass compositions. Infrared as well as green and blue upcon
version pumped fluorescences have been recorded under side light injec
tion.