ACTIVATION AND FUNCTIONALIZATION OF THE C-H BONDS OF METHANE AND HIGHER ALKANES BY A SILICA-SUPPORTED TANTALUM HYDRIDE COMPLEX

Authors
VIDAL V THEOLIER A THIVOLLECAZAT J BASSET JM
Citation
V. Vidal et al., ACTIVATION AND FUNCTIONALIZATION OF THE C-H BONDS OF METHANE AND HIGHER ALKANES BY A SILICA-SUPPORTED TANTALUM HYDRIDE COMPLEX, Journal of the Chemical Society, Chemical Communications, (10), 1995, pp. 991-992
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
10
Year of publication
1995
Pages
991 - 992
Database
ISI
SICI code
0022-4936(1995):10<991:AAFOTC>2.0.ZU;2-P
Abstract
Silica-supported tantalum hydride activates at low temperature the C-H and the C-D bonds of cyclooctane and CD4, respectively, to form the c orresponding cyclooctyl and perdeuteriomethyl-tantalum surface complex es; these complexes are transformed under molecular oxygen into the co rresponding tantalum-alkoxy derivatives which with acetic acid give ri se to the corresponding alkylacetates.