ALKYLATION OF [WS4](2-) - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE ETHYLTHIOLATOTRITHIOTUNGSTATE(VI) ANION

Authors
BOORMAN PM WANG MP PARVEZ M
Citation
Pm. Boorman et al., ALKYLATION OF [WS4](2-) - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE ETHYLTHIOLATOTRITHIOTUNGSTATE(VI) ANION, Journal of the Chemical Society, Chemical Communications, (10), 1995, pp. 999-1000
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
10
Year of publication
1995
Pages
999 - 1000
Database
ISI
SICI code
0022-4936(1995):10<999:AO[-SA>2.0.ZU;2-Z
Abstract
Reaction of [PPh(4)](2)[WS4] with ethyl bromide yields the tetraphenyl phosphonium salt of the title anion 1, for which an X-ray structure de termination reveals no evidence for an intramolecular redox reaction, but concentrated solutions undergo rapid reactions leading to [W3S9](2 -) and Et(2)S(x)(x = 1-3).