SYNTHESIS OF STABLE ALPHA,ALPHA'-BIS(CARBOXYMETHYL) SUBSTITUTED NITROXIDES VIA AN ORIGINAL DIANION-BASED STRATEGY

Authors
EINHORN J EINHORN C RATAJCZAK F PIERRE JL
Citation
J. Einhorn et al., SYNTHESIS OF STABLE ALPHA,ALPHA'-BIS(CARBOXYMETHYL) SUBSTITUTED NITROXIDES VIA AN ORIGINAL DIANION-BASED STRATEGY, Journal of the Chemical Society, Chemical Communications, (10), 1995, pp. 1029-1030
Citations number
27
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
10
Year of publication
1995
Pages
1029 - 1030
Database
ISI
SICI code
0022-4936(1995):10<1029:SOSASN>2.0.ZU;2-Q
Abstract
New stable nitroxides, analogous to TEMPO (tetramethylpiperidine-N-oxy l) where two alpha,alpha' methyl groups are formally replaced by ester functions, are prepared via dienolate chemistry followed by a deprote ction-oxidation sequence.