THE SYNTHESIS AND STRUCTURES OF C5H- AND C-5-

Citation
S. Dua et al., THE SYNTHESIS AND STRUCTURES OF C5H- AND C-5-, Journal of the Chemical Society, Chemical Communications, (10), 1995, pp. 1067-1068
Citations number
11
Categorie Soggetti
Chemistry
ISSN journal
00224936
Issue
10
Year of publication
1995
Pages
1067 - 1068
Database
ISI
SICI code
0022-4936(1995):10<1067:TSASOC>2.0.ZU;2-4
Abstract
The ion C5H- is formed in the gas phase by the process -(C=C)(2)CH(2)O Me --> C5H- + MeOH; ab initio calculations indicate a ground state tri plet structure with a near linear carbon skeleton, but with the termin al H at a marked angle to the carbon backbone.