THE PARALLEL BETWEEN PHENYL-INITIATED C-C COUPLING REACTIONS IN DIRHODIUM COMPLEXES AND THOSE CATALYZED BY RHODIUM PARTICLES

Authors
WANG ZQ LONG HC TURNER ML MAITLIS PM
Citation
Zq. Wang et al., THE PARALLEL BETWEEN PHENYL-INITIATED C-C COUPLING REACTIONS IN DIRHODIUM COMPLEXES AND THOSE CATALYZED BY RHODIUM PARTICLES, Journal of the Chemical Society, Chemical Communications, (10), 1995, pp. 1089-1091
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
10
Year of publication
1995
Pages
1089 - 1091
Database
ISI
SICI code
0022-4936(1995):10<1089:TPBPCC>2.0.ZU;2-P
Abstract
Decomposition of [{(C(5)Me(5))Rh(mu-CH2)}(2)(Ph)(CO)](+) (homogeneousl y, under CO) in solution gives PhCH=CH2, PhMe and C6H6, while phenyl ( from Phl) reacts with surface methylene (from CO + H-2) heterogeneousl y over rhodium metal to give PhEt, PhMe and C6H6; it is proposed that the two reactions are also related mechanistically.