HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF K(3)SB(3)A(2)O(14)CENTER-DOT-5H(2)O (A=P, AS)

Authors
AN YL FENG SH XU YH YUE Y
Citation
Yl. An et al., HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF K(3)SB(3)A(2)O(14)CENTER-DOT-5H(2)O (A=P, AS), Journal of materials chemistry, 5(5), 1995, pp. 773-776
Citations number
23
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
5
Issue
5
Year of publication
1995
Pages
773 - 776
Database
ISI
SICI code
0959-9428(1995)5:5<773:HSACOK>2.0.ZU;2-4
Abstract
K(3)Sb(3)A(2)O(14) . 5H(2)O (A=P, As) were synthesized by use of a hyd rothermal method, and the synthesis conditions are discussed in detail . Both phases were characterized by various techniques including scann ing electron microscopy, XRD, XPS, P-31 MAS NMR, IR, DTA-TG. The unit- cell parameters for K3Sb3P2O14 . 5H(2)O and K3Sb3As2O14 . 5H(2)O are s lightly smaller than those for the corresponding phases synthesized by solid-state reactions.