Rz. Hu et al., A NUMERICAL-METHOD OF COMPUTING THE KINETIC-PARAMETERS - EXOTHERMIC DECOMPOSITION OF ENERGETIC MATERIALS VIA THE EXOTHERMIC RATE-EQUATION, Journal of thermal analysis, 44(4), 1995, pp. 885-902
A numerical method of computing the kinetic parameters (the activation
energy (E), the preexponential constant (A) and the reaction order (n
)) of exothermic decomposition of energetic materials via the exotherm
ic rate equation is presented. The values of E, A and n are reported f
or the exothermic decomposition of six typical energetic materials, 1,
6-diazido-2,5-dinitrazahexane (I), 1,5-diazido-3-nitrazapentane (II),
2,2,4,7,9,9-hexanitro-5-methyl-4,7-dinitrazadecane (III), 2,2,2-trinit
roethyl-4,4,4-trinitrobutyrate (IV), 1,4-dinitro-2,3-dioxo-1,4-dinitra
zacyclohexane (V) and -trianitro-1,3,5-triazafurazano[3,4-f]cyclohepta
ne (VI).