SPIN-CROSSOVER AND THERMOCHROMISM IN COMPLEXES OF IRON(II) IODIDE ANDTHIOCYANATE WITH 4-AMINO-1,2,4-TRIAZOLE

Authors
LAVRENOVA LG YUDINA NG IKORSKII VN VARNEK VA OGLEZNEVA IM LARIONOV SV
Citation
Lg. Lavrenova et al., SPIN-CROSSOVER AND THERMOCHROMISM IN COMPLEXES OF IRON(II) IODIDE ANDTHIOCYANATE WITH 4-AMINO-1,2,4-TRIAZOLE, Polyhedron, 14(10), 1995, pp. 1333-1337
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
10
Year of publication
1995
Pages
1333 - 1337
Database
ISI
SICI code
0277-5387(1995)14:10<1333:SATICO>2.0.ZU;2-A
Abstract
New complexes of iron(II) iodide and thiocyanate with 4-amino-1,2,4-tr iazole were synthesized. The complexes were characterized by magnetic measurements, reflection, Mossbauer and IR spectra. The coordination o f iron(II) is discussed on the basis of these data. The compounds poss ess reversible thermochromism (colour change from white to pink) due t o the spin transition T-5(2) reversible arrow(1)A(1).