PREPARATION OF TRANSITION-METAL COMPLEXES OF CHIRAL DERIVATIVES OF ACETOACETIC ACID - TETRAALKYLAMMONIUM TETRACHLOROMETALLATES AS AN ORGANIC SOURCE OF METALS

Authors
GALVEZ N MORENOMANAS M PADROS I SEBASTIAN RM SERRA N VALLRIBERA A
Citation
N. Galvez et al., PREPARATION OF TRANSITION-METAL COMPLEXES OF CHIRAL DERIVATIVES OF ACETOACETIC ACID - TETRAALKYLAMMONIUM TETRACHLOROMETALLATES AS AN ORGANIC SOURCE OF METALS, Polyhedron, 14(10), 1995, pp. 1397-1399
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
10
Year of publication
1995
Pages
1397 - 1399
Database
ISI
SICI code
0277-5387(1995)14:10<1397:POTCOC>2.0.ZU;2-S
Abstract
Bis(benzyltrimethylammonium) tetrachlorocuprate, tetrachlorocobaltate and hexachlorodiferrate react in organic solvents with alkaline salts of CH3COCH2CO-X(c) [X(c)-H = (d)-menthol, (4S)-4-benzyl-2-oxazolidinon e and (2R)-bornane-10,2-sultam] to give homochiral beta-dicarbonyl met al complexes.