J. Yang et al., THE EFFECTS OF ALCOHOL WITH DIFFERENT CHAIN-LENGTH ON THE PHASE-EQUILIBRIA OF NONIONIC SURFACTANT SYSTEM, Journal of dispersion science and technology, 16(3-4), 1995, pp. 249-261
Addition of alcohol with longer chain length (C6H13OH, C8H17OH, and C1
2H21OH) caused a reduction the cloud point of a commercial nonionic su
rfactant, Tesgitol (T-15-s-9). The formation of lamellar liquid crysta
l (LLC) was favored so that isotropic liquid (L(1))-LLC two-phase regi
on became wider with increasing temperature at an appropriate weight r
atio of surfactant to alcohol. The isotropic liquid phase/liquid two p
hase transformation was replaced by a two-phase transformation to isot
ropic liquid/lamellar liquid crystal at the cloud point for the system
without alcohol.