SYNTHESIS, CHARACTERIZATION AND REACTIONS OF SODIUM MONOAZIDOETHYLENEDIAMINETETRAACETATOCOBALTATE(III)

Authors
BALASUBRAMANIAN N NATARAJAN P
Citation
N. Balasubramanian et P. Natarajan, SYNTHESIS, CHARACTERIZATION AND REACTIONS OF SODIUM MONOAZIDOETHYLENEDIAMINETETRAACETATOCOBALTATE(III), Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 34(6), 1995, pp. 481-483
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
34
Issue
6
Year of publication
1995
Pages
481 - 483
Database
ISI
SICI code
0376-4710(1995)34:6<481:SCAROS>2.0.ZU;2-G
Abstract
Sodium onoazidoethylenediaminetetraacetatocobaltate(III), (I) has been synthesized and characterized by elemental and spectral analysis. The presence of intramolecular hydrogen bonding is suggested based on pK( a) measurements. The kinetics of the acid hydrolysis of [Co(HEDTA)N-3] (-) to give [Co(EDTA)](-) is studied and the results are compared with those for [Co(HEDTA)X](-) ions where X = Cl or Br. The activation par ameters have also been calculated and the applicability of the compens ation law has been checked. A mechanistic scheme has been proposed for the acid-catalysed hydrolysis of the azido complex ion.