CHLORO BRIDGED BINUCLEAR RUTHENIUM(II) BETA-DIKETONATO COMPLEXES CONTAINING TRIPHENYLPHOSPHINE AND TRIPHENYLARSINE

Citation
G. Muthusamy et K. Natarajan, CHLORO BRIDGED BINUCLEAR RUTHENIUM(II) BETA-DIKETONATO COMPLEXES CONTAINING TRIPHENYLPHOSPHINE AND TRIPHENYLARSINE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 34(6), 1995, pp. 490-492
Citations number
15
Categorie Soggetti
Chemistry
ISSN journal
03764710
Volume
34
Issue
6
Year of publication
1995
Pages
490 - 492
Database
ISI
SICI code
0376-4710(1995)34:6<490:CBBRBC>2.0.ZU;2-J
Abstract
Binuclear ruthenium (II) complexes of the type [RuCl(EPh(3))(2) (beta dk)](2) (where E=P or As: beta dk=beta-diketonate) have been synthesiz ed from the reactions of fluorinated beta-diketones with [RuCl2(PPh(3) )(2)](n) and [RuCl2(AsPh(3))(2)](2). These complexes have been charact erized by elemental analyses, IR, (1)HNMR and electronic spectral data and an octahedral structure has been proposed for all the complexes.