G. Muthusamy et K. Natarajan, CHLORO BRIDGED BINUCLEAR RUTHENIUM(II) BETA-DIKETONATO COMPLEXES CONTAINING TRIPHENYLPHOSPHINE AND TRIPHENYLARSINE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 34(6), 1995, pp. 490-492
Binuclear ruthenium (II) complexes of the type [RuCl(EPh(3))(2) (beta
dk)](2) (where E=P or As: beta dk=beta-diketonate) have been synthesiz
ed from the reactions of fluorinated beta-diketones with [RuCl2(PPh(3)
)(2)](n) and [RuCl2(AsPh(3))(2)](2). These complexes have been charact
erized by elemental analyses, IR, (1)HNMR and electronic spectral data
and an octahedral structure has been proposed for all the complexes.