EFFECT OF CONCENTRATION ON OXIDATION POTENTIALS OF ALKYLARYLSELENIDES

Authors
JOUIKOV V POSTNIKOVA M
Citation
V. Jouikov et M. Postnikova, EFFECT OF CONCENTRATION ON OXIDATION POTENTIALS OF ALKYLARYLSELENIDES, Electrochimica acta, 40(7), 1995, pp. 803-807
Citations number
40
Categorie Soggetti
Electrochemistry
Journal title
Electrochimica acta → ACNP
ISSN journal
00134686
Volume
40
Issue
7
Year of publication
1995
Pages
803 - 807
Database
ISI
SICI code
0013-4686(1995)40:7<803:EOCOOP>2.0.ZU;2-Q
Abstract
For the processes of electrochemical oxidation of alkylarylselenides, implying the reversible electron transfer followed by potential-determ ining 1st order or 2nd order reaction (taking into account the concent ration dependence of E(1/2) due to consecutive kinetics), an extrapola tion of oxidation potentials to infinite diluted solution (C --> O) al lows the elimination of a non-specific adsorption contribution into th e effective E(1/2) value.