STANDARD GIBBS ENERGIES OF TRANSFER OF POTASSIUM TETRAPHENYLBORATE FROM WATER TO STRAIGHT-CHAIN N-ALKANOLS

Authors
ZOU LZ WANG XL ZHOU BX LI DC LI LW QU SS
Citation
Lz. Zou et al., STANDARD GIBBS ENERGIES OF TRANSFER OF POTASSIUM TETRAPHENYLBORATE FROM WATER TO STRAIGHT-CHAIN N-ALKANOLS, Journal of solution chemistry, 24(5), 1995, pp. 499-509
Citations number
28
Categorie Soggetti
Chemistry Physical
Journal title
Journal of solution chemistry → ACNP
ISSN journal
00959782
Volume
24
Issue
5
Year of publication
1995
Pages
499 - 509
Database
ISI
SICI code
0095-9782(1995)24:5<499:SGEOTO>2.0.ZU;2-I
Abstract
Solubilities of potassium tetraphenylborate in water, methanol, ethano l, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-octanol at 15, 25, 35, 45, 55 degrees C have been determined by spectrophotometry. Th e standard Gibbs energy of transfer of potassium tetraphenylborate for m water to straight-chain n-alkanols and the medium effect of potassiu m tetraphenylborate from 15 to 55 degrees C have been calculated. Furt hermore, the contribution of microscopic interactions to the standard Gibbs energy of transfer of potassium tetraphenylborate is calculated and discussed.