FT-IR spectrometer provided with software for multicomponent analysis
of IR spectra was used for simultaneous determination of up to 12 hydr
ocarbons in a gaseous mixture. The hydrocarbons, ranging from methane
to n-butane, were selected to simulate reaction product mixtures obtai
ned in the dehydrogenation of n-butane, The concentrations of the hydr
ocarbons in the sample were determined by fitting to the sample spectr
um a set of pure calibration spectra of the gases present in the sampl
e, In principle, the entire wavenumber range of the low-resolution IR
spectrum could be utilized in the fit, The reliability of the results
was checked from the residual spectrum, obtained by subtracting the fi
tted from the measured spectrum, The residual spectrum will be pure no
ise when the set of calibration spectra chosen for the analysis fits e
xactly with the sample spectrum, Precision of the results, expressed a
s average relative standard deviation, was +/-4%. Concentrations of mo
st of the hydrocarbons were determined with an error less than +/-10%,
The concentrations of isobutane, trans-2-butene, propane, and ethane
deviated by more than 10% from the reference concentrations, The sum c
oncentration of ethane and propane, however, deviated less than +/-1%
from the reference, Difficulties in determining ethane and propane acc
urately were due to the broad nature and small number of peaks in thei
r IR spectra, IR spectrometry with multicomponent analysis of spectra
provides a rapid and powerful method with potential for the study of c
atalytic reactions at a time resolution of seconds.