PHOTOCHEMISTRY OF A STRUCTURALLY UNCOMPLICATED PHENYLCARBYNE COMPLEX

Authors
TRAMMELL S SULLIVAN BP HODGES LM HARMAN WD SMITH SR THORP HH
Citation
S. Trammell et al., PHOTOCHEMISTRY OF A STRUCTURALLY UNCOMPLICATED PHENYLCARBYNE COMPLEX, Inorganic chemistry, 34(11), 1995, pp. 2791-2792
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
11
Year of publication
1995
Pages
2791 - 2792
Database
ISI
SICI code
0020-1669(1995)34:11<2791:POASUP>2.0.ZU;2-Q
Abstract
[Os(NH3)(5)CPh](O3SCF3)(3) is the first example of an Os carbyne that is luminescent in fluid solution. In CH3CN the complex exhibits a broa d emission centered at 632 nm with a lifetime of 55 ns. Of note is a u nique base-induced quenching process that occurs with substituted pyri dines.