PREPARATION AND MAGNETIC-PROPERTIES OF AL(PF3)(2)

Authors
HOWARD JA JONES R TOMIETTO M JOLY HA
Citation
Ja. Howard et al., PREPARATION AND MAGNETIC-PROPERTIES OF AL(PF3)(2), Inorganic chemistry, 34(11), 1995, pp. 3097-3098
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
11
Year of publication
1995
Pages
3097 - 3098
Database
ISI
SICI code
0020-1669(1995)34:11<3097:PAMOA>2.0.ZU;2-0
Abstract
Al(PF3)(2) is produced by reaction of ground-state Al atoms with PF3 i n an adamantane matrix at 77 K in a rotating cryostat. This new Al(0) complex has the magnetic parameters a(Al)(1) = 87 MHz, a(p)(2)= 160 MH z a(F)(6) = MHz, and g = 2.0040, values that are consistent with a(2)B (1) ground-state in C-2v symmetry.