Vm. Ovsyannikov et al., THE STATE OF SURFACE-LAYERS ON LITHIUM IN MODIFIED NONAQUEOUS MEDIA, Russian journal of electrochemistry, 31(4), 1995, pp. 324-328
The state of lithium electrode surface after contact with triethylamin
e-modified propylene carbonate solutions of lithium perchlorate was st
udied using the pulse galvanostatic technique as well as methods of SI
MS and electron microscopy. It was shown that amine added into the sol
utions stabilizes the state of lithium and prevents the formation of a
secondary porous passive film on the lithium surface. Chemical compos
ition of the primary film remains unchanged. Certain properties of pas
sive films formed in electrolyte solutions studied were evaluated.