POROUS-ELECTRODES AND PROTOTYPES OF SECONDARY CELLS BASED ON A NOVEL ELECTROCHEMICAL SYSTEM GRAPHITE-HBF4-ANTHRAQUINONE

Authors
BARSUKOV VZ BARSUKOV IV BECK F MOTRONYUK TI
Citation
Vz. Barsukov et al., POROUS-ELECTRODES AND PROTOTYPES OF SECONDARY CELLS BASED ON A NOVEL ELECTROCHEMICAL SYSTEM GRAPHITE-HBF4-ANTHRAQUINONE, Russian journal of electrochemistry, 31(4), 1995, pp. 398-402
Citations number
7
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
31
Issue
4
Year of publication
1995
Pages
398 - 402
Database
ISI
SICI code
1023-1935(1995)31:4<398:PAPOSC>2.0.ZU;2-3
Abstract
Porous electrodes and experimental prototypes of rechargeable batterie s based on a novel electrochemical system graphite-HBF4 + tetrafluorob orate additives-anthraquinone are developed. Intercalation of anions i n the graphite electrode is studied in detail and the intercalation po tential is determined (E(i) similar to 1.55 V vs. Ag-AgCl). Side react ions proceeding concurrently with primary current-generating processes at the electrodes are described. Feasibility of hermetically sealing a battery based on the new system due to anthrahydroquinone's ability to reduce oxygen that evolves during charging is demonstrated.