PREPARATION OF A CATION-EXCHANGER BASED O N CROSS-LINKED PARTIALLY PHOSPHORYLATED POLY(VINYL ALCOHOL) AND ITS SELECTIVITY FOR CATIONS

Authors
AN Y KOYAMA T HANABUSA K YAMADA A SHIRAI H IKEDA J YONENO H
Citation
Y. An et al., PREPARATION OF A CATION-EXCHANGER BASED O N CROSS-LINKED PARTIALLY PHOSPHORYLATED POLY(VINYL ALCOHOL) AND ITS SELECTIVITY FOR CATIONS, Kobunshi ronbunshu, 52(5), 1995, pp. 294-298
Citations number
3
Categorie Soggetti
Polymer Sciences
Journal title
Kobunshi ronbunshu → ACNP
ISSN journal
03862186
Volume
52
Issue
5
Year of publication
1995
Pages
294 - 298
Database
ISI
SICI code
0386-2186(1995)52:5<294:POACBO>2.0.ZU;2-U
Abstract
A strong acid cation exchange resin was prepared by crosslinking parti ally phosphorylated poly(vinyl alcohol) with glutaraldehyde. The ion e xchange capacity of the dry cation exchange resin in hydrogen form is 2.86 meq/g-resin. The rate of ion exchange is rapid and the solution p asses effectively through the resin column. The equilibrium distributi on coefficients in the resin for various cations at various pH values using various hydrochloric acid and ammonium aqueous solutions were me asured. Ions Fe(III) and Cu(II) or Cr(III) loaded on a column can be c ompletely separated from each other by elution with 0.1 mol/l HCl.