STUDIES ON THE REACTION OF N-BROMOSUCCINIMIDE IN DIMETHYL-SULFOXIDE .9. ACTION ON MORETENYL ACETATE

Authors
PRADHAN BP GHOSH RK CHAKRABORTY S MOTHEY J
Citation
Bp. Pradhan et al., STUDIES ON THE REACTION OF N-BROMOSUCCINIMIDE IN DIMETHYL-SULFOXIDE .9. ACTION ON MORETENYL ACETATE, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 34(6), 1995, pp. 492-495
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
34
Issue
6
Year of publication
1995
Pages
492 - 495
Database
ISI
SICI code
0376-4699(1995)34:6<492:SOTRON>2.0.ZU;2-E
Abstract
The action of N-bromosuccinimide on moretenyl acetate (1) in dimethyl sulphoxide affords 30-bromomoretenyl acetate (1a), 22,29,30-tribromomo retanyl acetate (2a) and 29,30-dibromo-22-hydroxymbretan-3 beta-yl ace tate (2b). 2a on adsorption over basic alumina for 7 days furnishes 1a , 2b, 30-bromomoretenol (1b), and E/Z-29-bromomoretenols (1c + 1d).