SYNTHESIS OF RUH2(CO)(PPH(3))(3) IN A CO2 AND H-2 ATMOSPHERE

Authors
ZHANG JZ WANG H LI Z WANG CY
Citation
Jz. Zhang et al., SYNTHESIS OF RUH2(CO)(PPH(3))(3) IN A CO2 AND H-2 ATMOSPHERE, Transition metal chemistry, 20(2), 1995, pp. 118-119
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
20
Issue
2
Year of publication
1995
Pages
118 - 119
Database
ISI
SICI code
0340-4285(1995)20:2<118:SORIAC>2.0.ZU;2-6
Abstract
RuH2(CO)(PPh(3))(3) was prepared in a CO2 and H-2 atmosphere from RuCl 3 and PPh(3) in the presence of alcohol and Et(3)N. Introduction of CO into the system lead to the formation of other complexes e.g. Ru(CO)( 3)(PPh(3))(2). Addition of alkali in place of Et(3)N resulted in a dec rease in the RuH2(CO)(PPh(3))(3) yield.