ON THE PREPARATION OF 1H-PERFLUOROALKANES AND A MECHANISM FOR THE REDUCTION OF PERFLUOROALKYL IODIDES

Authors
HOWELL JL MUZZI BJ RIDER NL ALY EM ABOUELMAGD MK
Citation
Jl. Howell et al., ON THE PREPARATION OF 1H-PERFLUOROALKANES AND A MECHANISM FOR THE REDUCTION OF PERFLUOROALKYL IODIDES, Journal of fluorine chemistry, 72(1), 1995, pp. 61-68
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
72
Issue
1
Year of publication
1995
Pages
61 - 68
Database
ISI
SICI code
0022-1139(1995)72:1<61:OTPO1A>2.0.ZU;2-#
Abstract
1H-Perfluoroalkanes are prepared by sodium methoxide reduction of 1-io doperfluoroalkanes. The experimental evidence indicates that the react ion proceeds either through a radical or a thermal mechanism. We have found that a high yield of 1H-perfluoroalkanes at complete conversion can be accomplished at atmospheric pressure using this technology.