The atmospheric corrosion of aluminium and zinc samples exposed at six
test sites with known ambient parameters in Argentina was investigate
d after different outdoor exposition periods. Corrosion damage was det
ermined by weight-loss measurements. Both D.C. and A.C. electrochemica
l techniques, performed in 0.1 M Na2SO4 solution employing the exposed
face of the test samples, were used to characterize the protectivenes
ses of the surface layers generated on the metals at different exposur
e times during the atmospheric corrosion process in the distinct envir
onments. The time dependence of corrosion rates as compared with the w
eight-loss data as well as with information from SEM and EDAX observat
ions of the rusts concerning the structure and morphology of surface c
orrosion products and the presence of pollutants.